RE: regress in crystallographic good practices and knowledge

2015-05-08 Thread Julian Richard Tolchard
I also agree that it serves a purpose, even though it is much quieter compared to when i first joined many years ago. I would not want to see it closed down, as there are questions coming up from time to time that would be very hard to get answered anywhere else. As Kurt suggests โ€“ why not just

RE: 3D powder averaging...

2015-05-10 Thread Julian Richard Tolchard
Is there perhaps a case for extending the scope of the mailing list? I'm sure many of us are active with non-Rietveld methods of analysing x-ray and neutron scattering data. Perhaps the list could expand accordingly and become something like the "X-ray and Neutron Scattering mailing list"? joo

RE: polarization

2015-06-03 Thread Julian Richard Tolchard
I seem to remember i asked the same question about Goebel mirrors last year. The outcome of that, from the list and a private comm or two, was that they are theoretically challenging to calculate because they effectively act as a series of monochromators with varying acceptance angles. The good

RE: Cyberstar hot air blowers

2015-07-03 Thread Julian Richard Tolchard
I bought Leister Mini a couple of years ago. It is a complete system (excluding an air supply) for around 2500 CHF purchased here. It doesn't blow a lot of hot air, but more than enough to heat up a capillary. The TC is not particularly sophisticated either, and i don't think has the option of e

RE: Proposal to avoid banning for attachments in the list

2015-07-15 Thread Julian Richard Tolchard
There is a reality here that the web is really a shifting sands of information. So the idea we link to images and files we wish to refer to is probably flawed, and is not going to achieve the "archive" role that would be desirable, simply because those links will be broken or lost in a few month

Quantitative internal standards

2015-10-08 Thread Julian Richard Tolchard
Hi all, I've been asked to do some quantification on some samples which are predominantly silica, which means a reasonable amorphous component is pretty much inevitable. I'm thus looking for a suitable internal standard for spiking, but as this could be quite a big project moving forwards i don

RE: Aking for Advice - reduce the current to X-ray tube to avoid director saturation at low angels

2016-03-06 Thread Julian Richard Tolchard
Shay, Can we assume you are working with a reflection mode instrument? You have two primary sources of background - the primary beam hitting the detector directly, and x-rays scattering from the air rather than the sample. The first of these you control with the divergence slits, but really sho

RE: Parafocussing definition?

2016-05-02 Thread Julian Richard Tolchard
The prefix "para-" has several definitions, one of which is "abnormal, incorrect" or "resembling". I assumed this prefix was used because BB geometry uses the focusing condition but is not truly a focusing geometry: The diffractometer circle and focusing circle being different causes the focusin

RE: atomic position

2016-06-14 Thread Julian Richard Tolchard
As a point of semantics, how exactly is copyright enforced with respect to the content of these databases? The crystal structures are in most cases published elsewhere, so there is no way that ICDD or ICSD can "own" them in any way. And even if claimed they did, can a crystal structure actually

Topas reporting macro

2016-12-11 Thread Julian Richard Tolchard
Hi all, A quick question - does anyone know an easy way to export the individual fits for xo_Is type peaks in Topas? I just want a 2 column file for each peak (or a collated file of all) that i can plot. I can't find anything in the documentation and my usual info repository (John Evans' To

RE: using Zero

2017-03-29 Thread Julian Richard Tolchard
I would also suggest that it is easier to just check that your instrument zero is aligned than to mess around with long scans and fitting routines to separate correlated variables. Jools -Original Message- From: rietveld_l-requ...@ill.fr [mailto:rietveld_l-requ...@ill.fr] On Behalf O

RE: [EXTERNAL] Mounting Sample on High Temperature XRD Ribbon Heater

2019-07-25 Thread Julian Richard Tolchard
Actually, i wouldn't recommend that either ๐Ÿ˜Š My experience with the Ta heaters is that they react with even the smallest amount of oxygen, and bottled N2 has more than enough to kill a Ta strip. The best result we had was with a H2/N2 mix, but that still failed (probably reaction with the sampl

RE: [EXTERNAL] Mounting Sample on High Temperature XRD Ribbon Heater

2019-07-25 Thread Julian Richard Tolchard
onsumables" and live with the associated cost. I know this is difficult for a lot of university labs, but once you adopt that mindset you can do much more interesting experiments. Jools From: Payzant, Andrew Sent: torsdag 25. juli 2019 17.08 To: Julian Richard Tolchard ; Mibeck, Blaise

RE: Bruker D8-Discover

2019-10-24 Thread Julian Richard Tolchard
Davide, It seems to me that burning out 3 control boards in a short space of time is obviously abnormal for any instrument. I would recommend talking directly to Bruker about it. jools From: rietveld_l-requ...@ill.fr On Behalf Of Davide Levy Sent: onsdag 23. oktober 2019 10.29 To: rietveld

RE: Hyper-Lorentzian effect on quantitative analysis

2021-03-03 Thread Julian Richard Tolchard
Thinking a little outside of the crystallographic aspects, do you have element analysis data? Either XRF or ICP-MS would give a good guide to the sample composition, and it should match to the composition you are using in the structure model. I find it is worth drying both the sample and spike

RE: recommended questions to XRD supplier.

2023-06-14 Thread Julian Richard Tolchard
My personal recommendations from instrument purchasing are: 1. Ask them for a full list of accessories available and a price list. Often you just donโ€™t realise what useful accessories they sometimes have available. 2. Software licences: Buying a new instrument is a good time to get them b

RE: Misconduct

2024-01-12 Thread Julian Richard Tolchard
That is impressive, but I'm sorry to say that I have seen worse. EM images though, not diffraction patterns. From: rietveld_l-requ...@ill.fr On Behalf Of Le Bail Armel Sent: fredag 12. januar 2024 12:57 To: Rietveld_L Subject: Misconduct Hi, A good candidate for the "worst Rietveld refinem