> So my question remains: what is the definition of signal to noise ratio > that is accepted for powder diffraction?
Why does it matter? A higher Bragg/Background ratio does not necessarily mean better data if counting statistics are poor. Exaggerating slightly :-) consider a single peak with a ratio of 100/1 compared to a peak with a ratio 10000/1000. The second measurement will give the lowest error, not the first which has a much higher signal/noise. And you measure lots of points on a slowly varying background, so you have a much better estimate of background than the normal error of a single point. Please don't encourage people to simply maximise "signal/noise". Similarly, low profile R-factor's can be obtained with low resolution data and high background. That does not mean that low resolution data produces smaller errors in structural parameters. I worry about people treating measurement and refinement as black boxes with simplified measures of quality such as R-factors, signal-to-noise etc. You have to look at the physical reality of the model and the estimated errors in its parameters, while not cheating by removing data that doesn't fit for unknown reasons, adding too much "a priori" information such as constraints, or throwing in extra garbage parameters to improve the R-factors. ______________________________________________ Dr Alan Hewat, NeutronOptics, Grenoble, FRANCE <[EMAIL PROTECTED]> +33.476.98.41.68 http://www.NeutronOptics.com/ ______________________________________________