This is a long shot, but I had a remotely similar problem once on a 
Maillard freewheel once and it was a loose cog within the freewheel. The 
cog wiggled around enough so that the chain wouldn't engage and skip. Mind 
you this was an inner cog from a crazy modification I did to the body (non 
standard). It was a rebuildable freewheel so it may not apply to you. Check 
that each cog is tight in the freewheel and make sure the freewheel is 
tight on the hub. For kicks I would also make sure there isn't a tight link 
in the chain, though you would see problems in other cogs but it wouldn't 
hurt to check. 

Other than that I am at a loss as to why you get the skipping. 

Good luck with finding the solution. 

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