If one does ORG->HTML->DOC instead of ORG->ODT->DOC, following areas
could be problemsome.
- Footnotes
- Inlined images - do they end up right within the document or outside
  of it.

See:
http://www.libreoffice.org/download/release-notes/
https://wiki.documentfoundation.org/ReleaseNotes/3.5#ODF_1.2_Conforming_Documents
https://bugs.freedesktop.org/show_bug.cgi?id=44498

,---- 
| Microsoft Office 2010 will complain that ODF 1.2 and extended documents
| written by LibreOffice 3.5 are invalid (but opens them still). This is a
| shortcoming in MSO2010 only supporting ODF 1.1, please see here for
| further details.
|
| ODF 1.2 Conforming Documents
| 
|     LibreOffice 3.5 writes valid ODF 1.2
| 
|     Microsoft Office only officially supports ODF 1.1 and complains that
|     ODF 1.2 and ODF 1.2 extended documents written by LibreOffice 3.5
|     are invalid.
| 
|     The warning from Microsoft Office can be safely ignored, and the
|     "Repair" option will import the document.
| 
|     For users that find this annoying, a workaround is to open
|     Tools->Options->Load/Save->General and set "ODF format version" to
|     "1.0/1.1". However, please note that this will cause some
|     information to be lost when storing documents.
`----

Instead of importing ODT documents right inside Microsoft Office, one
can have LibreOffice do the ODT->DOC(X) conversion and import the LO
created DOC(X) file in to Microsoft Office.

For creating DOC/DOCX/PDF files right from Org see Info node with
following title: (org) Extending ODT export.

ps: I have not used MS Word at all.
-- 

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