Could be a case of modeler bias. Just look at the name of the institute. This is like having a Jessie Helms endowed chair in the therapeutic benefits of tobacco.

On Aug 8, 2008, at 8:31 AM, Jacob Keller wrote:

Dear crystallographers,

although many laughed off one CCP4BB poster's comments several months ago as an April fools' trick (he had proposed that Bijvoet had actually botched the job, as I remember), there is now apparently experimental evidence against that trick:

"Was Bijvoet right? Sodium rubidium (+)-tartrate tetrahydrate revisited.Lutz M, Schreurs AM. Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.

The first determination of the absolute configuration of an organic compound was published in 1951 on sodium rubidium (+)-tartrate tetrahydrate, Na(+).Rb(+).C(4)H(4)O(6)(2-).4H(2)O, but the atomic coordinates are not available in the public literature. This structure has therefore been redetermined using current equipment. The most up-to-date techniques for the determination of the absolute configuration have been applied and the question posed in the title can be answered with an unequivocal ;yes'."

JPK

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Jacob Pearson Keller
Northwestern University
Medical Scientist Training Program
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