For X-ray/Synchrotron: That depends from the difference of the atomic
numbers Z between A and B. If A and B are neighbors in the periodic
table, nearly impossible. If the difference is large, you may go down
to percents.
In the case of neighbors in the periodic table, there is the option
of using neutron diffraction.

Joerg

Am Mittwoch, den 02.12.2009, 12:53 +0530 schrieb deepti kothari:
> Hi All,
>  
> Can anyone suggest me --Up to what dopant level (in any system like
> ABO3) one can conclusively determine from Rietveld refinement location
> of dopant as A or B site based on site occupancy.
>  
> Thanks in advance
> 
> Deepti Kothari 
> UGC-DAE,CSR, 
> INDORE 
> 
> 
> 
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