Good evening,
I have a question about Miller indexes (h k l) in
the space group R-3c (n° 167):
in the article Chem. Mater. 2003, 15, 2084-2093 the
authors writes:
<<The XRD patterns clearly show reflections
such as (3 0 3) which is normally forbidden in the R-3c space group... the space
group is unambiguously R-3 rather than R-3c..>>.
I can't understand why (3 0 3) is forbidden in
R-3c, since the general reflection condition is: -h+k+l=3n.
But this rule is present also in the space group
R-3 (n°148) !
And what does it means <<normally
forbidden >> ?
Does 'n' must be always
different from zero?
Thanks a lot for explanations,
marco
Marco Sommariva
Department of Materials Science University of Milano - Bicocca Via R. Cozzi 53 - 20125 MILAN, ITALY Phone +39.02.6448.5141 (5142) Fax +39.02.6448.5400 e-mail: [EMAIL PROTECTED] |
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