Good evening,
I have a question about Miller indexes (h k l) in the space group R-3c (n° 167):
in the article Chem. Mater. 2003, 15, 2084-2093 the authors writes:
<<The XRD patterns clearly show reflections such as (3 0 3) which is normally forbidden in the R-3c space group... the space group is unambiguously R-3 rather than R-3c..>>.
 
I can't understand why (3 0 3) is forbidden in R-3c, since the general reflection condition is:  -h+k+l=3n.
But this rule is present also in the space group R-3 (n°148) !
And what does it means <<normally forbidden >> ?
Does 'n' must be always different from zero?
Thanks a lot for explanations,
marco
 
 
 
Marco Sommariva
Department of Materials Science
University of Milano - Bicocca
Via R. Cozzi 53 - 20125 MILAN, ITALY
Phone +39.02.6448.5141 (5142)
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