On 2022-03-30 07:32, Nikolaos Milas wrote:
It seems as if these mails are not delivered successfully, but I
cannot see them in any queue either.

Delivered mail is deleted from the Postfix queue.  It would have been
moved out of Postfix by some means, such as a delivery agent or an
external transport(5) like smtp(8).

How can I troubleshoot these? What may be going wrong?

syslog_name is your friend.  I noticed none of your log lines had any
syslog_name other than the default.

Postfix will have a default smtpd(8) instance (usually the one on 25,
listening for mail arriving from outside) and also a default smtp(8),
the client process delivering mail to external MX hosts.

Any OTHER instance of these should have a descriptive syslog_name set
in master.cf:
...   ...   ...   ...   smtpd
    -o ...
    -o syslog_name=postfix/whatever
    -o ...
Where "whatever" describes the purpose of that listener or transport.

http://www.postfix.org/postconf.5.html#syslog_name

See also the sample master.cf as distributed in source code.
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  http://rob0.nodns4.us/

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