It appears that Wietse Venema <postfix-users@postfix.org> said:
>According to Exim documentation (link below) the '!' and '%' are
>not special in email addresses, so we know that at least it does
>not appear to break legitimate usage.

Technically, that is correct.  According to the local-part syntax in RFCs 5321 
and 5322,
you can use all these characters, and also dots that are not at the beginning 
or end:

   atext           =   ALPHA / DIGIT /    ; Printable US-ASCII
                       "!" / "#" /        ;  characters not including
                       "$" / "%" /        ;  specials.  Used for atoms.
                       "&" / "'" /
                       "*" / "+" /
                       "-" / "/" /
                       "=" / "?" /
                       "^" / "_" /
                       "`" / "{" /
                       "|" / "}" /
                       "~"

On the other hand, if you try to use addresses that contain ! or % you will be
in endless pain, because MTAs all over the world treat them as attempts to do
relaying and reject them.

I would go back and ask what problem they are trying to solve, because this 
probably
is not the right way to solve it.

R's,
John

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