Jools, as David Burgin pointed out, your SPF record in DNS is (still)
broken (as well as your DMARC record) and this may well be the cause
of your problems.
v=spf1 mx a:81.145.130.2 -all
should be (because the 'a:...' syntax is wrong and superfluous):
v=spf1 mx -all
- I missed this on my original reading oops

For the DMARC record, remove the escaped quotes:
\"v=DMARC1; p=none; rua=mailto:sysad...@bordengrammar.kent.sch.uk\";
should be:
v=DMARC1; p=none; rua=mailto:sysad...@bordengrammar.kent.sch.uk


On Sat, 12 Sep 2020 at 19:17, Julian Pilfold-Bagwell
<j...@bordengrammar.kent.sch.uk> wrote:
>
> Hi,
>
> I've fixed DKIM and have fired a message off to several DKIM validation
> sites which have come back with SPF, DMARC and DKIM as all having
> passed.   I changed the TLS setting you suggested as well
>
> We then sent a test batch and the first 11 went through, the following 8
> were rejected, and the next 7 went through.
>
> It really is weird.  If it was all of the messages being bounced I could
> understand it, but google and yahoo both seem to let a load through yet
> block a handful.  I guess it's possible that the end-users have an
> option to set the aggressiveness of the spam filtering but it seems like
> a setting that wouldn't be commonly used as Google's defaults are
> usually pretty good and we don't tend to get rejected in daily use.
>
>
> On 12/09/2020 14:53, Dominic Raferd wrote:
> > Just after I sent my reply to your later email I saw this reply of
> > yours (below) - which Google had accepted but put into my spam folder!
> >
> > On Sat, 12 Sep 2020 at 13:14, Julian Pilfold-Bagwell
> > <j...@bordengrammar.kent.sch.uk> wrote:
> >>    I'll make the change to TLS and see what happens as well as fix the
> >> DMARC.  The server's been running 24/7 since 2015 and is due for
> >> replacement in the summer of 2021 at which point I'll be upgrading the
> >> postfix version.
> >>
> >> I'll check the headers again and will get back.
> >>
> >> On 12/09/2020 12:15, Dominic Raferd wrote:
> >>> On Fri, 11 Sep 2020 at 22:49, Julian Pilfold-Bagwell
> >>> <j...@bordengrammar.kent.sch.uk> wrote:
> >>>> I have a problem that's sprung to light after we bought in a 3rd party
> >>>> cloud provider.  I have postfix 2.10 running on Centos 7 (main.cf below)
> >>>> and our 3rd party provider is relaying mail out via our server, using
> >>>> authentication on a legit account.  However, the recipient ISPs reject
> >>>> mail with the error 554 5.7.1 recipient access denied, although this
> >>>> doesn't seem to happen on all the messages that are being sent.  If
> >>>> we're sending say 60 messages, the first block of 20 will go through,
> >>>> the next 20 will be blocked and the final 20 will go through.  I'm
> >>>> guessing that the receiving end is objecting to something in the headers
> >>>> from the relayed mail, but can't quite get to grips as to why it occurs
> >>>> in batches.
> >>>>
> >>>> The 3rd party provider is sending reports to all of our end users which
> >>>> is over a thousand emails+  so I've limited the delivery rate to 1
> >>>> message per domain every twenty seconds  to try to appear less spammy
> >>>> but it still happens as described.  The error message is as below:
> >>>>
> >>>> NOQUEUE: reject: RCPT from smtp.overnetdata.com[5.153.65.228]: 554 5.7.1
> >>>> <usern...@hotmail.com>: Recipient address rejected: Access denied;
> >>>> from=<edul...@bordengrammar.kent.sch.uk> to=<usern...@hotmail.com>
> >>>> proto=ESMTP helo=<www7>
> >>>>
> >>>> and we're receiving this from talktalk.co.uk, sky.com, yahoo.co.uk,
> >>>> hotmail.com, outlook.com and gmail.com sometimes talks to us, and
> >>>> sometimes doesn't.
> >>>>
> >>>> and main.cf is shown here:...
> >>> The setup seems imperfect, and the version of postfix rather old, but
> >>> which if any of the imperfections is causing this new problem is hard
> >>> to say without fuller examples of what is being blocked, which I can
> >>> well understand you might not want to post on an open forum. My
> >>> observations are:
> >>>
> >>> Instead of 'smtp_use_tls = yes' it is advisable to use
> >>> 'smtp_tls_security_level = may' (Postfix 2.3+)
> >>>
> >>> Your SPF entry in DNS looks ok, provided as you say that the 3rd party
> >>> is sending your emails via your mail server and not independently.
> >>> Also your mail server's ip is not blacklisted at any of the 129 rbls I
> >>> regularly check, nor at https://ipremoval.sms.symantec.com/. You can
> >>> check its status with Microsoft by registering it at their Smart
> >>> Network Data Service.
> >>>
> >>> Your DMARC entry in DNS is broken, also you do not appear to be
> >>> signing outgoing emails with DKIM. But I doubt either of these is the
> >>> explanation for your problem.
> >>>
> >>> Is the third party sender using your domain in the 'From:' header as
> >>> well as in the envelope?
> >> --
> >> J. Pilfold-Bagwell,

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