> Is it possible to determine the Mail User Agents in use via logging in 
> Postfix and / or Dovecot?

Assert you're using header-checks with pcre in main.cf:

header_checks = pcre:/etc/postfix/header_checks


Then add the following to /etc/postfix/header_checks and reload postfix:

/^(User-Agent|X-Mailer):/    INFO 


This prints a log line like:

Jul 23 00:34:24 mx2.server.com postfix/cleanup[11568]: 4BBqyS5c2CzTVVPX: info: 
header X-Mailer: Apple Mail (2.3445.104.14) from client.provider.com[1.2.3.4]; 
from=<sen...@domain.com> to=<recipi...@otherdomain.com> proto=ESMTP 
helo=<PCNAME>

This might be sufficient for your case but keep in mind what Ralph and Paolo 
said.

Best regards
Gerald

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