If you want maildir style delivery for UNIX accounts, specify 

/etc/postfix/main.cf:
    mail_spool_directory = /var/mail/

Documentation:

mail_spool_directory (default: see postconf -d output)
       The directory where local(8) UNIX-style mailboxes are kept. The default
       setting depends on the system type. Specify a  name  ending  in  /  for
       maildir-style delivery.

        Wietse

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