I want to use port 25025 for outgoing messages. I modified 
/etc/postfix/master.cf as follows but postfix will not reload.

smtp      inet  n       -       n       -       -       smtpd
25025     init  n       -       n       -       -       smtpd

Strangely it works with port 2525. In both cases I opened the ports in iptables.

Server on CentOS 6.8 and Plesk 12.5

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