On Thu, Jul 28, 2016 at 08:29:00PM +0200, Benny Pedersen wrote:

> Jul 28 18:24:13 localhost postfix/smtpd[20024]: warning: TLS library
> problem: error:14094412:SSL routines:ssl3_read_bytes:sslv3 alert bad
> certificate:s3_pkt.c:1472:SSL alert number 42:

Thunderbird does not trust the server certificate, get a certificate
it trusts.  Perhaps the certificate uses SHA1 or MD5, or perhaps its
issuer is not trusted?  Or the hostname does not match, or the chain
file is missing an intermediate certificate, ...

You need to post the certificate chain and the Thunderbird SMTP
settings for further help.

-- 
        Viktor.

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