i...@itrezero.it:
> if web client (a web application) connects to xxx.yyy.zzz.79 => emails are
> sent through xxx.yyy.zzz.79 (instance 1), 
> 
> if it connects to xxx.yyy.zzz.80 => emails are sent through xxx.yyy.zzz.80
> (instance 2), 

Here you talk about the IP address that Postfix uses to receive mail.

> Everything worked properly, I thought! Until I discovered some complaints
> messages from Yahoo that say:
> 
> 421 4.7.0 [TS01] Messages from xxx.yyy.zzz.79 temporarily deferred due to
> user complaints <-- from INSTANCE 1 IP address
> 
> BUT I sent messages through xxx.yyy.zzz.80 that is IP address of instance
> (2)!!!.

Here you talk about the IP address that Postfix uses to send
mail.

To fix the source IP address for sending mail either:

- Specify smtp_bind_address in the respective main.cf files.

or:

- Specify ONE address with the inet_interfaces parameters
  in the respective main.cf files.

        Wietse

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