Marco Fioretti:
> a) is it possible to tell postfix at example.com that all and only the
> email from someuser with a From: address of someu...@someotherdomain.com
> should be relayed through that MTA, not directly to destination? (I am
> almost sure it is, as I said my first problem is to know/use the right
> search
> terms for this function, sorry)

Maybe this:
http://www.postfix.org/postconf.5.html#sender_dependent_relayhost_maps

> b) would it work, as far as SPF and DKIM are concerned? Would it cause
> other problems?

Does your system have "relay" permissions at the other domain's mail
server? You may have to configure SASL auth and
"smtp_sender_dependent_authentication = yes".

        Wietse

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