Am 18.11.2013 17:36, schrieb Dominique:
> Nov 18 17:10:15 mail postfix/smtp[20654]: 2937521D41:
> to=<x...@gmail.com>, relay=smtp.isp.es[1.1.1.1]:25, delay=1.1,
> delays=0.09/0/0.87/0.18, dsn=5.0.0, status=bounced (host
> smtp.isp.es[1.1.1.1] said: 522 Authenticate first (in reply to MAIL FROM
> command))
> 
> I understand that I need to authenticate first for the relayhost to kick
> in, and I thought I had it. (Applied the same logic from the cyrus
> setup), but it seems I missed something.
> 
> Can someone give me a hint ?

smtp_sasl_auth_enable = yes
is nowhere in your posted configuration

notice smtp_ versus smtpd_ while anyhting which is
relevant for sending message sto another MTA is smtp_

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