On 9/10/2011 2:37 PM, Ryan Blakeslee wrote:
> A summary of the problem. 
> -------------------------
> 
> Hello,
> I am new to the list but a long time Postfix user.  I have am trying to
> accomplish the following, but am unsure of how to exactly go about doing
> it.  I need to re-direct a few specific recipient addresses to a host
> other than the relay host I have Postfix send to (that relay host for
> our domain that Postfix delivers to being Exchange Server.)


Use transport_maps entries to direct mail to an alternate location.

# transport
other.example.com  relay:[smtp.other.example.com]
u...@example.com  relay:[smtp.example.com]

http://www.postfix.org/transport.5.html


  -- Noel Jones

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