A customer is migrating their mail environment, and in the interim a bit of 
trickery is needed.

They are currently using a Postfix+Mailscanner machine as a gateway per the 
http://www.postfix.org/STANDARD_CONFIGURATION_README.html#firewall

Now, how would I realize a scenario where SOME users of a domain is to be 
directed to 172.31.254.160 and SOME to 172.31.254.150?

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