ren yufei:
> Oct 19 16:07:45 ubuntu postfix/local[23073]: 9422DA070A: 
> to=<renyufe...@gmail.co
> m>, relay=local, delay=0.46, delays=0.19/0.05/0/0.22, dsn=5.1.1, 
> status=bounced
> (unknown user: "renyufei83")

You are sending mail for GMAIL.COM to the LOCAL delivery agent.
This usually means that by mistake you added gmail.com to
your local destination list:

mydestination = hash:/etc/postfix/mydomains

Remove gmail.com (and other remote destinations) from this file.

        Wietse

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