I'm able to use Postfix to send mail to e.g. GMail accounts:

Apr 26 22:41:14 blog postfix/pickup[14939]: 49ACD8081A: uid=1000 from=<ejain>
Apr 26 22:41:14 blog postfix/cleanup[14969]: 49ACD8081A:
message-id=<20100426224114.49acd80...@...>
Apr 26 22:41:14 blog postfix/qmgr[4627]: 49ACD8081A: from=<ej...@...>,
size=352, nrcpt=1 (queue active)
Apr 26 22:41:15 blog postfix/smtp[14972]: 49ACD8081A:
to=<[email protected]>,
relay=gmail-smtp-in.l.google.com[209.85.217.51]:25, delay=1.1,
delays=0.02/0.01/0.31/0.71, dsn=2.0.0, status=sent (250 2.0.0 OK
1272321675 19si6283624gxk.13)
Apr 26 22:41:15 blog postfix/qmgr[4627]: 49ACD8081A: removed


But when I log in as a different user on the same machine, Google's
mail server no longer accepts mail (the reverse DNS lookup test
appears to fail):

Apr 26 22:38:58 blog postfix/pickup[14939]: E5ECD8081A: uid=33 from=<www-data>
Apr 26 22:38:58 blog postfix/cleanup[14951]: E5ECD8081A:
message-id=<20100426223858.e5ecd80...@...>
Apr 26 22:38:58 blog postfix/qmgr[4627]: E5ECD8081A:
from=<www-d...@...>, size=355, nrcpt=1 (queue active)
Apr 26 22:39:30 blog postfix/smtp[14953]: E5ECD8081A:
to=<[email protected]>, relay=gmail-smtp-in.l.google.com[74.125.67.27]:25,
delay=31, delays=0.03/0.03/0.34/31, dsn=5.7.1, status=bounced (host
gmail-smtp-in.l.google.com[74.125.67.27] said: 550-5.7.1 [...] The IP
you're using to send mail is not authorized 550-5.7.1 to send email
directly to our servers. Please use the SMTP relay at 550-5.7.1 your
service provider instead. Learn more at                          550
5.7.1 http://mail.google.com/support/bin/answer.py?answer=10336
a22si14294522anp.42 (in reply to end of DATA command))
Apr 26 22:39:30 blog postfix/cleanup[14951]: 2C6138081B:
message-id=<20100426223930.2c61380...@...>
Apr 26 22:39:30 blog postfix/bounce[14962]: E5ECD8081A: sender
non-delivery notification: 2C6138081B
Apr 26 22:39:30 blog postfix/qmgr[4627]: 2C6138081B: from=<>,
size=2826, nrcpt=1 (queue active)
Apr 26 22:39:30 blog postfix/qmgr[4627]: E5ECD8081A: removed
Apr 26 22:39:30 blog postfix/local[14964]: 2C6138081B:
to=<www-d...@...>, relay=local, delay=0.02, delays=0.01/0/0/0.01,
dsn=2.0.0, status=sent (delivered to mailbox)
Apr 26 22:39:30 blog postfix/qmgr[4627]: 2C6138081B: removed


Any idea what could be going on here?

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