Sean Reifschneider:
> On 03/24/2010 10:36 AM, Randy wrote:
> > EX:
> > <r...@theholycat.com>: Sender address rejected: Domain not found (in
> > reply to RCPT TO command))
> 
> I'd be tempted to set up a milter or policy filter that for each rcpt
> would connect to the Exchange server (assuming that's where it's destined)
> and see if that server will accept it.  There's probably a better way to do
> it, but that's what comes to my mind.

You could also use Postfix's built-in recipient address verification feature.

http://www.postfix.org/ADDRESS_VERIFICATION_README.html#recipient

        Wietse

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