Here is another possibility with Postfix version 2.6 and later.

Cron job at midnight:
postconf -e master_service_disable=inet (or: smtp.inet)
postfix reload

Cron job at 07:00:
postconf -e master_service_disable=
postfix reload

There are many other uses of cron that would also achive the
desired effect.

        Wietse

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