Unleess you can hand over the certificate that Postfix complained
about, you have not proven that Postfix was in error. 

Specifically, yout tests with curl and openssl s_client may have
used a different IP address than Postfix, because the smtp.gmail.com
IP address changes frequently.

The smtp.gmail.com A record has a TTL of 300s, but it changes every
few seconds (it not only depends on when you ask, it also depends
on where you are). Here is a small sample, asked from an IP address
near New York city:

    Fri Mar 22 04:54:12 PM EDT 2024 172.253.62.109
    Fri Mar 22 04:54:13 PM EDT 2024 172.253.62.109
    Fri Mar 22 04:54:14 PM EDT 2024 172.253.62.108
    Fri Mar 22 04:54:16 PM EDT 2024 172.253.62.109
    Fri Mar 22 04:54:17 PM EDT 2024 172.253.62.108
    Fri Mar 22 04:54:18 PM EDT 2024 172.253.62.108
    Fri Mar 22 04:54:19 PM EDT 2024 172.253.62.108
    Fri Mar 22 04:54:20 PM EDT 2024 172.253.62.109
    Fri Mar 22 04:54:21 PM EDT 2024 172.253.62.109
    Fri Mar 22 04:54:22 PM EDT 2024 172.253.62.108
    Fri Mar 22 04:54:23 PM EDT 2024 172.253.62.108

Even if your tests did use the same IP address as Postfix, each
connection may be serviced by a different backend behind a load
balancer.

Even if you connected to the same backend, its configuration may
have changed. Like other providers, Google rolls out (SMTP) server
updates frequently. It updates a few servers and if the error rate
remains small it updates more servers, otherwise it rolls back the
change.

        Wietse
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