Many thanks! That should get me going.
The interfaces are apparently numbered ("smtpd1", "smtpd2") in main.cf in the order they appeared in master.cf while the "smtpd" remains the default (unless disabled). If I disable the default in master.cf, does the first interface-specific smtpd become "smtpd" without a suffix or does it remain enumerated since it's not generic? I'll find that out in a few moments, but I'm guessing it remains enumerated because otherwise smtpd_* params in main.cf would not refer to a specific interface as would be intended, and there would not be a way to define global smtpd_* parameters.