Really good write up Sid. I have always been suspicios that VinylEster may not 
be 100% Ethanol proof. There are also Ethanol resistant sloshing compounds, but 
while they are resistant, they are not Ethanol Proof. Seems to me there was a 
post a couple of years ago on here about a highly recommended Ethanol "proof" 
slosh compound.

 FWIW, I built my tanks with SafetyPoxy some 16 years ago and they have been in 
service for 15 years and some 900 flight hours. I also sloshed them with what 
would now be considered to be a lower grade alcohol resistant sloshing 
compound. I did run some alcohol through the tanks back when the plane was new, 
but haven't had any in the tanks in 15 years now. Since then, it has had a 
steady diet of 100LL with the exception of one tank full of 80/87 red gas I was 
able to buy about 10 years ago. After 15 years, the tanks and sloshing compound 
all appear to be in excellent condition with no slosh or tank residue in the 
sumps. But, I very specifically avoid mogas so as to avoid any chance of 
alcohol contamination. Those with Aluminum tanks probably have a much better 
tolerance for alcohol contamination.

 A couple of years ago I rebuilt the tip tanks off from a Cherokee 235. Those 
tanks were built with polyester resin. Teh owner of the plane swore that he 
always tested his fuel for alcohol and had never observed any alcohol in the 
fuel he had put in the plane. The tip tanks had become so soft that they were 
deforming in flight. When I cut them open, I found the inner layer of the tanks 
to be pretty much melted away with pockets of gas held within the glass all 
over the tanks. I ground out the pockets as best I could and literally built a 
new tank within the old tank shells so they would hold fuel. However, with the 
amount of fuel saturation in the outer shell of the tanks, he found that they 
simply could not be cleaned up well enough to hold paint. For all practical 
purposes, he really should have replaced the tanks with new, which was a 6 
month lead time and $6000 for two tip tanks.

 -Jeff Scott
 Los Alamos, NM



----- Original Message -----
From: Sid Wood
Sent: 07/12/12 08:52 AM
To: kr...@mylist.net
Subject: KR> Ethanol Compatibility

 I remember Mark Langford saying that public confessions were good for the soul 
or something like that. That also makes it more difficult to get elected to 
political office. I am looking for neither of those concerns. I once 
recommended building fiber glass fuel tanks using Vinyl Ester Resin. All 
sources that I could find did say that Vinyl Ester was compatible with the 
Ethanol found in most automobile fuels today. Conversely, Epoxy was not 
compatible with Ethanol. I built the wing tanks in my Diehl wing skins using 
Vinyl Ester Resin per the Diehl instructions. When I put in 92-octane auto fuel 
containing 10 percent Ethanol, I got the same reaction as if the tanks were 
made with Epoxy. Surfaces slowly started to dissolve, fuel turned yellowish 
brown and a sticky brown goo starting clogging the sumps. I researched my 
sources on the internet and all still confirmed my previous conclusion. Looking 
a little further on solvency chemistry, I found internet sites that address 
ways to enhance solvent action. Pure Ethanol, gasoline and water are excellent 
solvents by themselves, but none of these alone will effect cured Vinyl Ester. 
Adding 6 percent water to Ethanol will produce a solvent that will slowly 
dissolve Vinyl Ester. So, how much water would that actually be in auto fuel 
containing 10 percent Ethanol? The math is easy: 10 percent of 6 percent is 0.6 
percent. That's less than 1 ounce per gallon. Where does the water come from? 
From the moisture in the air, the Ethanol will readily adsorb the water in half 
full tanks, especially if there is a vent like most aircraft tanks (like mine). 
I now have drained the tanks and left the caps off. After 2 weeks the goo on 
the inside surfaces has "re-cured" hard just like the original. The 
quick-drains had become clogged and have been replaced. One concern is the 
integrity of the tank walls; there is an imprint of the foam layer sandwiched 
between the inner and outer wing surface, top and bottom, that outlines the 
wing tanks. This imprint pattern appeared when the drying out process was 
started. Any ideas what is going on with that? Long term plan now is to use 
100LL. Sid Wood Tri-gear KR-2 N6242 Mechanicsville, MD, USA 
smw...@md.metrocast.net _______________________________________ Search the 
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