http://www.autoblog.com/2015/12/31/nanoparticle-enhanced-magnesium-vehicle-lightweighting/
Nanoparticle-enhanced metals could radically change cars
Dec 31st 2015  Jonathon Ramsey

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Scientists at UCLA have found a new way to inject silicon carbide
nanoparticles into a molten alloy of magnesium and zinc, resulting a metal
nanocomposite that demonstrates "record levels" of stiffness-to-weight and
specific strength, and "superior stability" at high temperatures. Magnesium
is already the lightest structural metal, this lab creation maintains its
light weight but makes it much stronger. The researchers said they also
developed a scalable manufacturing process, opening up a door to lighter and
stronger cars, planes, medical devices, and electronics.

Silicon carbide is the ultra-hard material used in car clutches and carbon
ceramic brakes. Nanoparticles have been injected into molten metal before,
but the particles tend to clump together. The UCLA breakthrough came in
getting silicon carbide nanoparticles to spread evenly throughout the molten
magnesium, then using high-pressure torsion to compress the resulting metal
and make it even stronger. By weight, the alloy is 14 percent silicon
carbide, 86 percent magnesium. Head researcher Xiaochun Li said this first
successful effort is "just scratching the surface of the hidden treasure for
a new class of metals with revolutionary properties and functionalities."


This advance could be part of the solution to stricter corporate average
fuel economy dictates on the way. On the alt-fuel side, being able to
produce a lighter, stronger electric-vehicle chassis would help overcome
some of the weight of the battery pack. Nevetheless, while the researchers
say magnesium is abundant and they have a scalable manufacturing method, the
question is, 'At what price?' The press release below has more.


UCLA researchers create exceptionally strong and lightweight new metal

Magnesium infused with dense silicon carbide nanoparticles could be used for
airplanes, cars, mobile electronics and more

December 23, 2015 - A team led by researchers from the UCLA Henry Samueli
School of Engineering and Applied Science has created a super-strong yet
light structural metal with extremely high specific strength and modulus, or
stiffness-to-weight ratio. The new metal is composed of magnesium infused
with a dense and even dispersal of ceramic silicon carbide nanoparticles. It
could be used to make lighter airplanes, spacecraft, and cars, helping to
improve fuel efficiency, as well as in mobile electronics and biomedical
devices.

To create the super-strong but lightweight metal, the team found a new way
to disperse and stabilize nanoparticles in molten metals. They also
developed a scalable manufacturing method that could pave the way for more
high-performance lightweight metals. The research was published today in
Nature.

"It's been proposed that nanoparticles could really enhance the strength of
metals without damaging their plasticity, especially light metals like
magnesium, but no groups have been able to disperse ceramic nanoparticles in
molten metals until now," said Xiaochun Li, the principal investigator on
the research and Raytheon Chair in Manufacturing Engineering at UCLA. "With
an infusion of physics and materials processing, our method paves a new way
to enhance the performance of many different kinds of metals by evenly
infusing dense nanoparticles to enhance the performance of metals to meet
energy and sustainability challenges in today's society."

Structural metals are load-bearing metals; they are used in buildings and
vehicles. Magnesium, at just two-thirds the density of aluminum, is the
lightest structural metal. Silicon carbide is an ultra-hard ceramic commonly
used in industrial cutting blades. The researchers' technique of infusing a
large number of silicon carbide particles smaller than 100 nanometers into
magnesium added significant strength, stiffness, plasticity and durability
under high temperatures.

The researchers' new silicon carbide-infused magnesium demonstrated record
levels of specific strength — how much weight a material can withstand
before breaking — and specific modulus — the material's stiffness-to-weight
ratio. It also showed superior stability at high temperatures.

Ceramic particles have long been considered as a potential way to make
metals stronger. However, with microscale ceramic particles, the infusion
process results in a loss of plasticity.

Nanoscale particles, by contrast, can enhance strength while maintaining or
even improving metals' plasticity. But nanoscale ceramic particles tend to
clump together rather than dispersing evenly, due to the tendency of small
particles to attract one other.

To counteract this issue, researchers dispersed the particles into a molten
magnesium zinc alloy. The newly discovered nanoparticle dispersion relies on
the kinetic energy in the particles' movement. This stabilizes the
particles' dispersion and prevents clumping.

To further enhance the new metal's strength, the researchers used a
technique called high-pressure torsion to compress it.

"The results we obtained so far are just scratching the surface of the
hidden treasure for a new class of metals with revolutionary properties and
functionalities," Li said.

The new metal (more accurately called a metal nanocomposite) is about 14
percent silicon carbide nanoparticles and 86 percent magnesium. The
researchers noted that magnesium is an abundant resource and that scaling up
its use would not cause environmental damage.

The paper's lead author is Lian-Yi Chen, who conducted the research as a
postdoctoral scholar in Li's Scifacturing Laboratory at UCLA. Chen is now an
assistant professor of mechanical and aerospace engineering at Missouri
University of Science and Technology.

The paper's other authors from UCLA include Jia-Quan Xu, a graduate student
in materials science and engineering; Marta Pozuelo, an assistant
development engineer; and Jenn-Ming Yang, professor of materials science and
engineering.

The other authors on the paper are Hongseok Choi, of Clemson University;
Xiaolong Ma, of North Carolina State University; Sanjit Bhowmick of
Hysitron, Inc. of Minneapolis; and Suveen Mathaudhu of UC Riverside.

The research was funded in part by the National Institute of Standards and
Technology.
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