Lee has discussed this in the past, it is likely in the archives.
I see three main issues:
- at lower voltage, the zener knee gets very soft so unless you use additional 
electronics to amplify, the zener itself does not work very well on a single 
cell as you already indicated, two cells might indeed be better since around 6V 
the zeners have the best characteristics but that introduces issues with 
imbalance between the two cells
- Voltage differences while charging are very small with most types of Lithium. 
3.2V at rest but 3.5V is over-charging a LiFePO4 cell whereas a flooded/AGM 
lead-acid battery can easily go from 12V to 15V and it does not hurt them to be 
sitting at 15V while balancing for an hour.
- leakage and failure: while zeners are supposed to go "on" at a certain 
voltage, they will leak below that voltage so you are introducing extra 
"self-discharge" which can very per cell with the properties of the zener, so 
in a sense you are making the situation for Li-Ion worse. Also zeners can fail 
(shorted typically) and mechanically fail and the Lithium cells will not take 
well to being over-charged due to a failure

Cor van de Water
Chief Scientist
Proxim Wireless

office +1 408 383 7626          Skype: cor_van_de_water
XoIP   +31 87 784 1130          private: cvandewater.info
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-----Original Message-----
From: EV [mailto:[email protected]] On Behalf Of damon henry via EV
Sent: Tuesday, June 23, 2015 10:37 AM
To: EV List
Subject: [EVDL] Lee Hart Zener Regulator for Calb cells

Hi,
I am wondering if anyone has adapted Lee Hart's Zener regulators for lithium 
cell use.  I don't think the voltage of one cell is high enough to use this 
type of device on, but I think proper values can be found to regulate two cells 
in series.  I would love to experiment with some of these and would like full 
bypass at 6.8 volts.  I believe the 12 volt model can be tweaked by picking 
appropriate replacement Zener diodes, but I don't do a lot of this type of 
design, so I am not familiar with what is available or where to source the 
parts.  Any help would be appreciated.
thanks Damon
Here is a link to Lee's design.http://www.sunrise-ev.com/LeesEVs.htm#zenerlamp  
                                  
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