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How to Make Hydrogen Gas Using Simple Materials

4 Methods

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Wikihow/CC BY-NC-SA 3.0
By Anne Marie Helmenstine, Ph.D.
Updated on July 15, 2024

It's easy to generate hydrogen gas at home or in a lab using common
household materials. Here's how to make hydrogen safely.

Make Hydrogen Gas—Method 1

One of the easiest ways to obtain hydrogen is to get it from water,
H2O. This method employs electrolysis, which breaks water into
hydrogen and oxygen gas.

Materials Needed

water
9-volt battery
2 paper clips
another container filled with water

Steps

Unbend the paper clips and connect one to each terminal of the battery.
Place the other ends, not touching, into a container of water. That's it!
You'll get bubbles off both wires. The one with more bubbles is giving
off pure hydrogen. The other bubbles are impure oxygen. You can test
which gas is hydrogen by lighting a match or lighter over the
container. The hydrogen bubbles will burn; the oxygen bubbles will not
burn.
Collect the hydrogen gas by inverting a water-filled tube or jar over
the wire producing the hydrogen gas. The reason you want water in the
container is so you can collect hydrogen without obtaining air. Air
contains 20% oxygen, which you want to keep out of the container to
keep it from becoming dangerously flammable. For the same reason,
don't collect the gas coming off both wires into the same container,
since the mixture could burn explosively upon ignition. If you wish,
you can collect the oxygen in the same way as the hydrogen, but be
aware this gas is not very pure.
Cap or seal the container before inverting it, to avoid exposure to
air. Disconnect the battery.

Make Hydrogen Gas—Method 2

There are two simple improvements you can make to improve the
efficiency of hydrogen gas production. You can use graphite (carbon)
in the form of pencil "lead" as electrodes and you can add a pinch of
salt to the water to act as an electrolyte.

The graphite makes good electrodes because it's electrically neutral
and won't dissolve during the electrolysis reaction. The salt is
helpful because it dissociates into ions which increase the current
flow.

Materials Needed

2 pencils
salt
cardboard
water
battery (could go as low as 1.5 V with the electrolyte)
2 paper clips or (better yet) 2 pieces of electrical wire
another container filled with water

Steps

Prepare the pencils by removing the eraser and metal caps and
sharpening both pencil ends.
You're going to use the cardboard to support the pencils in the water.
Lay the cardboard over your container of water. Insert the pencils
through the cardboard so that the lead is submerged in the liquid, but
not touching the bottom or side of the container.
Set the cardboard with pencils aside for a moment and add a pinch of
salt to the water. You could use table salt, Epsom salt, etc.
Replace the cardboard and pencils. Attach a wire to each pencil and
connect it to the terminals of the battery.
Collect the gas as in Method 1, in a container that has been filled with water.

Make Hydrogen Gas—Method 3

You can get hydrogen gas by reacting hydrochloric acid with zinc:

Zinc + Hydrochloric Acid → Zinc Chloride + Hydrogen
Zn (s) + 2HCl (l) → ZnCl2 (l)+ H2 (g)

Materials Needed

hydrochloric acid (muriatic acid)
zinc granules (or iron filings or strips of aluminum)

Hydrogen gas bubbles will be released as soon as the acid and zinc are
mixed. Be very careful to avoid contact with the acid. Also, heat will
be given off by this reaction.

Homemade Hydrogen Gas—Method 4

Aluminum + Sodium Hydroxide → Hydrogen + Sodium Aluminate
2Al (s) + 6NaOH (aq) → 3H2 (g) + 2Na3AlO3 (aq)

Materials Needed

sodium hydroxide (found in certain drain clog removers)
aluminum (included in the drain removal products or you can use foil)

This is an extremely easy method of making homemade hydrogen gas.
Simply add some water to the drain clog removal product! The reaction
is exothermic, so use a glass bottle (not plastic) to collect the
resulting gas.

Hydrogen Gas Safety

The main safety consideration is making certain hydrogen gas isn't
allowed to mix with oxygen in the air. Nothing bad will happen if it
does, but the resulting air-hydrogen mixture is much more flammable
than hydrogen on its own because it now contains oxygen, which will
act as an oxidizer.
Store hydrogen gas away from an open flame or another ignition source.

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