On 07/10/2016 12:07 PM, Paul Koning wrote:
On Jul 10, 2016, at 9:07 AM, Tothwolf <tothw...@concentric.net> wrote:

On Sun, 10 Jul 2016, Paul Birkel wrote:
Stated Tothwolf tothw...@concentric.net:

"Both contact surfaces must also be the same material or tin oxide will form on the 
surface of the gold plating and cause a major headache. This was a serious problem with 
486 and earlier Pentium PCs with 30 and 72 pin SIMMs and it led to a number of 
lawsuits."
Almost every DEC System Unit ("backplane") that I've ever seen uses
tinned-contacts, yet the Modules all use gold-plated fingers.
I'm not familiar with them used in DEC systems in that way, but the problems 
with mixing tin and gold plated connectors is well documented. Even the 
connector manufacturers warn against mixing different platings.
While "don't mix contact surfaces" is sufficient, it isn't necessary.  What matters is the 
"anodic index" of the metal, or rather, the difference between those two values for the two metals 
in contact.  If that difference is large, you have a problem; if it's small enough, you do not.  "Small 
enough" depends on the environment; aboard an oceangoing ship the number has to be smaller than in an 
office setting.  I remember looking into this topic for an investigation of what types of contact platings 
are acceptable for lithium coin cell battery holders in IT equipment.


This applies to bolted contact for structural things. Gold connectors usually have light contact pressure to preserve the soft gold plating. Tin contacts usually have higher contact force to scrape the oxide off the tin surface. When they are mixed, the tin can wipe onto the gold and then allow oxides to form due to the lower contact force. Tin contacts are supposed to provide enough pressure to form gas-tight contact areas.

And, of course, when exposed to salty air, then everything goes downhill REAL fast, corrosion galore. In a salt environment, I'd use semi-hermetically sealed connectors, and still expect lots of problems.
The Navy probably knows a LOT about these things.

Jon

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