You are cordially invited to join  ....

Kate Szerlag
Assistant Professor of Soil and Water Chemistry

Texas A&M University


Wednesday, December 11, 13:30 (EST)
in
"Advances in the use of synchrotron-based radiation for spatially resolved 
imaging and spectroscopy to speciate phosphorus in soils"
this is a Hybrid Meeting
In-Person
Building 745 (NSLS II) room 156
Register in advance for the virtual meeting:
https://bnl.zoomgov.com/meeting/register/vJIscOqvrT8qGMYwDpJEnvj5qyoLTjjiAwo    
  
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Abstract: As an essential plant nutrient, phosphorus (P) is often applied to 
agricultural fields in the form of animal manure or fertilizer. Excess P may 
become detrimental to aquatic ecosystems by causing eutrophication. By 
determining the solid-phase phosphorus (P) species present in high P 
agricultural soils, we may better understand P solubility and therefore 
availability to plants and environmental susceptibility to P losses. Although 
soil P has been extensively researched, direct evidence of the solid phase 
species is still a growing field due to limitations in direct speciation 
techniques. This presentation focuses on pairing wet chemical experiments with 
synchrotron-based, multi-modal techniques to speciate soil P solid phase 
species. Briefly, high resolution, micro-X-ray fluorescence (m-XRF) mapping 
followed by P K-edge micro-X-ray absorption near edge structure (µ-XANES) were 
collected of agricultural soils located on the Delmarva Peninsula (Delaware, 
USA) with high total P (digest in excess of 800 mg/kg). Using these samples, 
µ-XRF maps of the same soil thin section and powder mount locations were 
completed at the National Synchrotron Light Source II (NSLS-II) using beamlines 
8-BM and 4-BM. By utilizing the two beamlines, we were able to successfully 
demonstrate the spatial distribution and co-location of P with Al, Si, S 
(8-BM), Fe, Ca, and Mn (4-BM) on the soil thin sections and powder mounted 
samples. Following µ-XRF mapping, we used beamline 8-BM to probe P hotspots 
using P K-edge µ-XANES to determine P speciation at the micron scale.


=================
Vivian Stojanoff, PhD
Education, Training, Outreach
User Program
p 1(631) 344 8375
e lifescie...@bnl.gov<mailto:lifescie...@bnl.gov>
w https://www.bnl.gov/ps/lifesciences/<https://www.bnl.gov/ps/lsbr/>

Address:
Center for Biomolecular Structure
National Synchrotron Light Source II
Building 745
Brookhaven National Laboratory
Upton NY 11973





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