Hello, is the CSO going into the PDB file as ATOM'S or HETATM's?

Best wishes, Jon Cooper. [email protected]

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-------- Original Message --------
On 27 May 2023, 00:43, Nicholas Clark wrote:

> I have a cysteine residue that is oxidized and needs to be modeled as CSO. In 
> the past, when "replace residue" was used to substitute for CSO, the CSO 
> would "behave" during real-space refinement and essentially take the place of 
> the Cys. However, when Cys is replaced by CSO now the CSO is behaving as an 
> "external ligand" and does not maintain covalent bonds to the residue before 
> or after (repulsion between CSO & preceding and subsequent residue). The only 
> way I can get it to maintain covalent bonds in Coot is to add CSO as a 
> monomer and place it before merging into the chain and renumbering the 
> residue (afterwards, real space refinement behaves the same as direct 
> replacement of CYS->CSO). Similarly, during refinement with Refmac, only one 
> of the CSO conformations will maintain its position, the alternate 
> conformation breaks the linkage to the preceding residue.
>
> TLDR: CSO replacement of CYS not working in Coot or Refmac, acting as 
> external ligand.
>
> I've tried adding a "Link" definition to the header for both conformations 
> but this does not fix it. Any suggestions on how to resolve this issue?
>
> Best regards,
>
> Nick Clark
>
> --
>
> Nicholas D. Clark (He/Him)
> PhD Candidate
> Malkowski Lab
> University at Buffalo
> Department of Structural Biology
> Jacob's School of Medicine & Biomedical Sciences
> 955 Main Street, RM 5130
> Buffalo, NY 14203
>
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