Yes if it either

A) oligomerizes
B) significantly changes shape
C) aggregates reversibly

On option B: Lower NaCl could make the protein “appear” bigger by unfolding it 
a bit; hydrophobic interactions should be weaker in lower NaCl.

JPK





Artem
www.harkerbio.com<http://www.harkerbio.com>
"where wild SEC columns roam free"

On Jan 11, 2017 7:22 PM, "Reza Khayat" 
<[email protected]<mailto:[email protected]>> wrote:

Hi,



Sorry for the off-topic question. Can a protein in lower [NaC] run faster on a 
SEC than at higher [NaCl] (i.e. elute at an earlier volume)? The protein elutes 
well within the resolution limits of the SEC with a symmetric gaussian A280 
profile. I know that at lower [NaCl] the protein can elute later because it may 
interact with the matrix.  Thanks.



Best wishes,
Reza


Reza Khayat, PhD
Assistant Professor
City College of New York
Department of Chemistry
New York, NY 10031


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