It seems that the problem is more of general python problem than of web2py.

Before using string:list type field to store user-defined field, I didn't 
experience having dict key values as non-ascii. Because of the new problem 
definition, I did experience it and learned something new.

For just clearing the problem out of web2py: The problem of extra escape 
character added can be reproduced as below.

>>> a_dict = { '\xec\x9d' : '\xed\x95' }

>>> str(a_dict)
"{ '\\xec\\x9d' : '\xed\\x95' }"

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