Seems to be related to bug #225532.
Robbert, did you manually modify your locale settings?
Can you attach the output of the following command on a terminal:
$ locale
** Changed in: system-config-printer (Ubuntu)
Assignee: (unassigned) => Pascal De Vuyst (pascal-devuyst)
Status: New => Incomplete
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my-default-printer.py crashed with Error in setlocale()
https://bugs.launchpad.net/bugs/200756
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