According to the release notes of gutenprint, the Canon PIXMA iP4850 has 
(EXPERIMENTAL) support since version 5.2.9
Please try if the newer gutenprint 5.2.9+ included in vivid, 14.10 or 14.04 LTS 
solves your problem.
You can test without installing by using an ubuntu-desktop live-cd.

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https://bugs.launchpad.net/bugs/1442605

Title:
  first print wrong others fine

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