I see the same thing here in 15.04.

The Cntl+Fn keys are set to workspaces.

As a workround go to Workspace Settings and remove the combination(s)
from there before setting others.

(I actually use meta+F8 for Clementine Next )

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https://bugs.launchpad.net/bugs/1410760

Title:
  Can't assign Ctrl+Fn as global hotkey

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