After a few tests, I suspect the issue might come from the audio track.

If I encode without the audio track :
avconv -i P5270914.MOV -an P5270914-trusty-no-audio.webm

It gives me the attached file, and it plays fine on Firefox

When comparing both mkvinfo (the ones generated with libav, on Precise and 
Trusty), you can notice that the audio track has a different bit depth (32 vs 
16).
Maybe the header bit depth could not correspond to the actual bit depth of the 
track, or something similar?

** Attachment added: "WebM file generated on Trusty with libav, without any 
audio track"
   
https://bugs.launchpad.net/ubuntu/+source/libav/+bug/1323822/+attachment/4123650/+files/P5270914-trusty-no-audio.webm

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https://bugs.launchpad.net/bugs/1323822

Title:
  Firefox can not play some WebM videos generated by avconv on Trusty

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