I had the same issue, turns out the bug involved is pretty old and has
to do with alsa & pulseaudio: http://askubuntu.com/questions/118675
/mute-key-mutes-alsa-and-pulseaudio-but-unmutes-only-alsa

Quick and diry solution:
sed -i 's/amixer/amixer -D pulse/' ~/.config/openbox/lubuntu-rc.xml

When I fixed this, I discovered a concurrency bug in amixer; if you keep
the VolUp/Down button pressed, the new amixer command will get executed
before the old one has finished, leading to unbalanced volume in my
case.

I fixed this by executing ~/volup.sh, ~/voldown.sh and ~/volmute.sh
instead of the amixer commands in lbuntu-rc.xml, and having the
following scripts in my homedir:

~$ tail vol*sh
==> voldown.sh <==
#!/bin/bash
[ ! -e ~/amixerlock ] && touch ~/amixerlock && amixer -D pulse -q sset Master 
3%- && rm ~/amixerlock

==> volmute.sh <==
#!/bin/bash
[ ! -e ~/amixerlock ] && touch ~/amixerlock && amixer -D pulse -q sset Master 
toggle && rm ~/amixerlock

==> volup.sh <==
#!/bin/bash
[ ! -e ~/amixerlock ] && touch ~/amixerlock && amixer -D pulse -q sset Master 
3%+ && rm ~/amixerlock

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https://bugs.launchpad.net/bugs/1262572

Title:
  lxpanel volume control cannot be toggled mute/unmute with keyboard

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