I had a similar issue. But since I knew I had a fully capable nvidia card, I 
looked further and realized metacity composting wasn't enabled.
1) "gconf-editor" in terminal
2) apps -> metacity -> general
3) enable "composting-manager" by checking the box

worth checking out if your pretty sure your video card is capable of
handling Unity.

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https://bugs.launchpad.net/bugs/654347

Title:
  Unity doesn't start after reboot

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