Dianne,
My last response was short because I wanted to be under the message size
limit. Just to give you more info on silver chelates in general, here is
a study on the effectiveness of silver chelation with glutamic and
tartaric acids:
http://jac.oxfordjournals.org/cgi/content/full/54/2/546
I have no data on the safety of ingesting of these chelates although my
guess is that they are safe.
 
Here is a study on the effectiveness of silver citrate: 

http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2590638
<http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2590638> :

 

Relative to the compound below and the patent I referenced in my
previous response, you can indeed make it. The patent tells you how. If
it were me, I would only consider the EDTA chelate because I know EDTA
it is safe to take internally. I do not know about the other compound.
However, there is one problem with EDTA. EDTA is a fairly large molecule
and because of this only about 10 percent of any EDTA taken orally
actually passes through the intestinal wall and into the bloodstream. I
would expect a silver/EDTA chelate to be slightly larger and that may
yet reduce the bioavailability of the chelate. If I were to make it, I
would consider modifying the method to use another source of silver ions
such as EIS or silver oxide.

 

I hope Marshall is back on the list and he or Ode comment.

 

 - Steve N

 

________________________________

From: Dianne France [mailto:[email protected]] 
Sent: Thursday, April 30, 2009 7:04 AM
To: silver-list
Subject: CS>Chelated Silver


I copied the following from a web site.  There has been a lot about
chelated silver in our magazines and wanted to know how to make it if it
can be made at home?  Has
anyone had any experience making Chelated Silver?  Does it have draw
backs that our cs doesn't?
Dianne
 
 
Chelated Silver(tm) is silver ions in solution. It is vastly different
from the silver-based dietary supplement products known as colloidal
silver <http://nccam.nih.gov/health/silver/#> , which is silver in
suspension. In colloidal silver, finely divided particles of elemental
silver are randomly floating in suspension in water and are not evenly
dispersed. In CHELATED SILVER(tm), ions of pure, crystallized silver
nitrate are chemically bonded to nonmetallic ions, and are therefore
evenly dispersed throughout the solution. This bonding in solution
considerably enhances Chelated Silver(tm)'s antimicrobal action and
persistance (killing power over time).

In colloidal suspensions, minute silver particles of elemental silver
are suspended or randomly floating in water, typically at a level of
10-50 parts per million. Chelation occurs when a metal ion forms a
heterocyclic bond with a bidentate ligand. Examples of bidentate ligands
are carbonate and oxalate ions and ethylenediamine. As a general rule,
five- or six-member lingands are favored. Chelated Silver(tm) ions are
chemically bonded to nonmetallic ions and are evenly dispersed
throughout the solution. This concentrated and uniform dispersal of
Chelated Silver(tm) ions (typically at a level of 300 to 400 parts per
million) throughout the solution considerably enhances their
antimicrobial action, persistence and effectiveness.

Chelated Silver(tm) is highly effective in blocking the respiration of
microorganisms causing them to expire. Additionally,  scientific testing
is in progress to study the effectiveness of Chelated Silver(tm) in
interdicting anaerobic bacteria (bacteria that exists in the absence of
oxygen).