Hi Johannes, I have tried and that has not worked even before. The python-qgis.bat sets PYTHONHOME to `apps/Python39` runs `bin/python.exe`. When the `ensurepip` module is installing pip it installs it in isolated (`python.exe -I -m ensurepip`) mode that clears all the python related environment variables. So it is expected that bin/python.exe won't find standard libraries.
-Lauri
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