svdr:
> What can I do to find the reason for the timeouts?

You need to find out where in the SMTP protocol the timeout happens.

- TCP connection setup.

- SMTP Server '220' initial response.

- EHLO, MAIL FROM, RCPT TO, DATA, end-of-data.

Ideally, the PHP client would provide that information.

Postfix logging will show 'lost connection after XXX', but that
happens only for a completed TCP connection.

        Wietse

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