SW:
> Can someone assist me with troubleshooting this further please? I have been
> through the logs but I can't find any clue as to why this is happening.
> 
> I'd be happy to answer any questions about my main.cf or master.cf file.

What other warnings does Postfix log?
http://www.postfix.org/DEBUG_README.html#logging

Run smtpd under a non-interactive debugger and report output:
http://www.postfix.org/DEBUG_README.html#gdb

        Wietse

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