>
>
>
> I need to do the setup for High availability function.
>
> Also want to implement load balancing for 02 nodes.
>

You will have to build streaming replication which was introduced in
PostgreSQL-9.0


> I think PGPool will be require for that. Can I use PGPool without cost.
>

pgpool-II is an open source tool which can be used for connection pooling
and load balancing.


>  Can I get the basic steps to do this setup?
>
>
>
>                 Database        --          Postgresql 9.1
>
>              OS                 --          Linux 6
>

Below is the link which explains the basic steps to setup "streaming
replication"

https://www.postgresql.org/docs/9.1/static/warm-standby.html

By the way, version 9.1 is very old and will reach end-of-life soon. You
are 4 major versions behind, did you consider using latest version ?

Regards,
Venkata B N

Fujitsu Australia

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