Mark Williams wrote:

> Can anyone please shed any light on what more I need to do?

Overall, what you did looks good.
I've never used IIS, but when faced with similar problems with Apache,
ProcessExplorer [1] has been quite effective to figure out which
dependent DDLs were missing, where PHP was searching for them,
and the precise errors it encountered.

[1] https://docs.microsoft.com/en-us/sysinternals/downloads/process-explorer

Best regards,
-- 
Daniel Vérité
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