Hi Hao,
   I think your problem is that your directory's name is Chinese name ,not
English,please put your file in an English name folder.
Also for batch conversion ,maybe you can run in command line mode.

Hope this help.

Lirong

Message: 3
Date: Wed, 1 Sep 2010 12:38:47 +0800
From: hao wang <naz...@gmail.com>
Subject: [Open Babel] some problems about openBabel
To: openbabel-discuss@lists.sourceforge.net
Message-ID:
        <aanlktinm+0zz6=v1bk3urqrawxoxs5nf5_orp3+8r...@mail.gmail.com>
Content-Type: text/plain; charset="iso-8859-1"

Dear sir or madam,
      I just download a openBabel2.2.3.  I want to convert a .sdf file to
.mol file. BUT this programme tell me

==============================
*** Open Babel Error  in OpenBabel::OBConversion::OpenAndSetFormat
  Cannot open C:\Documents and Settings\Administrator\????\CID_91274.sdf
0 molecules converted

-- 
I don't know what happened on this. could you give me a hand?
I have put the sdf file into attachment. the file downloaded for PubChem.
thankyou!

Best wishes,
       Hao Wang
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