If the DVD is unprotected, it's sufficient just to create a disk image from the DVD using Disk Utility, and then burn that image to a blank DVD of sufficient size. Make sure that you choose "Master" (OS X extension .cdr) as your disk image format. Select the volume in Disk Utility that you want to clone, and then in the File menu of Disk Utility, the "Create disk image from ..." option. You can burn using the button in the toolbar.
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