Try \linebreak[4]\mbox{annoyinglongunbreakableword}. You can put the whole thing
in a TeX box, or put everything up to and including the first brace in a TeX
box, the unbreakable mess in ordinary text, and the trailing brace in another
TeX box.

Footnotes in captions is an unholy mess. Try googling it and you'll see.

Paul



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