I have discovered that the same error also occurs when i go to "tools > Tex 
information" and do a
rescan. The problem occurs when there is no spaces in the directory too. and 
I'm not running from
a usb stick.

No, currently the path is 'E:/WSSCI/bibtex/wssci.bst'. This is a folder on a
USB drive.

Then please update you MiKteX-installation using MiKTeX's update wizard program (available in via Windows' start menu, requires an open internet connection). Run the update program twice if necessary.
Does it then work?

regards Uwe

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